Coconut shell-derived activated carbon-enhanced water phase change material for cold thermal energy storage.

In building cooling, the demand for cooling surges during specific times, stressing air-conditioner operation, and additional cooling is often wasted during low-demand periods. Water-phase change material (W-PCM)-based thermal energy storage (TES) allows for load shifting and effective management of peak demand by storing cooling energy when the demand is low. This stored energy can be deployed during peak hours, decreasing energy usage and associated CO2 emissions. However, the use of W-PCMs was hindered by phase separation, slow energy transfer, and high supercooling degree (SCD). We synthesized coconut shell (CNS)-produced activated carbon (ACC) to use as a thermal enhancer in W-PCMs for the first time. First, ACC was synthesized from CNS via steam activation. Then, transmission electron microscopy was used to confirm the pore morphology of the CNS-ACC. The synthesis of the W-PCM with various weight percentages (0.1, 0.6, and 1.2) of CNS-ACC was accomplished in two steps. Zeta potential distribution analysis revealed that the W-PCM with CNS-ACC exhibited colloidal stability. Thermal conductivity (TC) and thermogram analyses revealed that a dose of 1.2 wt% CNS-ACC enhanced liquid and solid TC by 9% and 22%, respectively, despite a 6% and 8% decrease in specific heat and latent heat. More specifically, solidification assessment in a spherical enclosure revealed 100% suppression of SCD with 1.2 wt% CNS-ACC. As a result of this and the enhanced TC, the overall solidification process was accelerated, reducing the overall duration by 18.5%. Thus, the combination of CNS-derived ACC and W-PCM for TES in building cooling could reduce energy consumption and associated CO2 emissions.

Unlocking the Potential of Porous Bi2Te3-Based Thermoelectrics Using Precise Interface Engineering through Atomic Layer Deposition.

Porous thermoelectric materials offer exciting prospects for improving the thermoelectric performance by significantly reducing the thermal conductivity. Nevertheless, porous structures are affected by issues, including restricted enhancements in performance attributed to decreased electronic conductivity and degraded mechanical strength. This study introduces an innovative strategy for overcoming these challenges using porous Bi0.4Sb1.6Te3 (BST) by combining porous structuring and interface engineering via atomic layer deposition (ALD). Porous BST powder was produced by selectively dissolving KCl in a milled mixture of BST and KCl; the interfaces were engineered by coating ZnO films through ALD. This novel architecture remarkably reduced the thermal conductivity owing to the presence of several nanopores and ZnO/BST heterointerfaces, promoting efficient phonon scattering. Additionally, the ZnO coating mitigated the high resistivity associated with the porous structure, resulting in an improved power factor. Consequently, the ZnO-coated porous BST demonstrated a remarkable enhancement in thermoelectric efficiency, with a maximum zT of approximately 1.53 in the temperature range of 333-353 K, and a zT of 1.44 at 298 K. Furthermore, this approach plays a significant role in enhancing the mechanical strength, effectively mitigating a critical limitation of porous structures. These findings open new avenues for the development of advanced porous thermoelectric materials and highlight their potential for precise interface engineering through the ALD.

Difference of Microbial Community in the Stream Adjacent to the Mixed Antibiotic Effluent Source.

Released antibiotics from source to stream can influence bacterial communities and potentially alter the ecosystem. This research provides a comprehensive examination of the sources, distribution, and bacterial community dynamics associated with varied antibiotic release sources adjacent to the stream. The residual of antibiotics from different sources was determined, and the bacterial community structure was examined to reveal the differences in the bacteria community in the stream. The residual of antibiotics was quantified with liquid chromatography-tandem mass spectrometry (LC-MS/MS), and the Illumina MiSeq platform was utilized to sequence bacterial 16S rRNA genes, providing comprehensive insights into the bacterial community structure in the sediment across five different sites. Results indicated that the presence and distribution of antibiotics were significantly influenced by released sources. In the case of the bacterial community, the Proteobacteria and Firmicutes were the most dominant phyla in the sediment, and especially, the Firmicutes showed higher abundance in sites mostly affected by livestock sources. Additionally, livestock gut bacteria such as Clostridium saudiense, Proteiniclasticum ruminis, and Turicibacter sanguinis were prevalent in antibiotic-contaminated sites adjacent to livestock facilities. Overall, this study provides critical insights into the effect of antibiotic contamination by verifying the relationship between the occurrence of antibiotic residuals and the alteration in the bacterial community in the stream.

Alginate-encapsulated biochar as an effective soil ameliorant for reducing Pb phytoavailability to lettuce (Lactuca sativa L.).

The alginate-biochar formulation for metal removal from aquatic environments has been widely tried but its use for lowering phytoavailability of metals in the soil-crop continuum is limited. Biochar has been increasingly used as a soil amendment due to its potential for soil carbon sequestration and sorption capacity. Handling of powdery biochar as a soil top-dressing material is, however, cumbersome and vulnerable to loss by water and wind. In this experiment, biochar powder, which was pyrolyzed from oak trees, was encapsulated into beads with alginate, which is a naturally occurring polysaccharide found in brown algae. Both batch and pot experiments were conducted to examine the effects of the alginate-encapsulated biochar beads (BB), as compared to its original biochar powdery form (BP), on the Pb adsorption capacity and phytoavailability of soil Pb to lettuce (Lactuca sativa L.). The BB treatment improved reactivity about six times due to a higher surface area (287 m2 g-1) and five times due to a higher cation exchange capacity (50 cmolc kg-1) as compared to the BP treatment. The maximum sorption capacity of Pb was increased to 152 from 81 mg g-1 because of surface chemosorption. Adsorption of Pb onto BB followed multiple first-order kinetics and comprised fast and slow steps. More than 60% of the Pb was adsorbed in the fast step, i.e., within 3 h. Also, the BB treatment, up to the 5% level (w/w), increased soil pH from 5.4 to 6.5 and lowered the phytoavailable fraction of Pb in soil from 5.7 to 0.3 mg kg-1. The Pb concentrations in lettuce cultivated at 5% for the BP and BB treatments were similar but 63 and 66% lower, respectively, than those of the control soil. The results showed that the encapsulation of biochar with alginate enhanced adsorption by the biochar.

A MATLAB simulation-based analytical study of energy, exergy, and cost benefits in jet-impinged protrusion-roughened double pass solar air collector.

This study analyzes the performance and cost-effectiveness of a protrusion-roughened jet-impinged double-pass solar air collector (PRJDPSAC) within a Reynolds number (Re) range of 2500 to 22,500. Examining jet slot parameters, i.e., the jet height ratio (Hjp/Dhd = 0.11-0.44), stream-wise pitch ratio (Xjp/Dhd = 0.44-1.32), and span-wise pitch ratio (Yjp/Dhd = 0.44-1.32), the model demonstrates enhanced energy conversion, minimizes losses, improves efficiency, and brings positive economic impact, making it a promising solution for diverse applications including drying processes, livestock facilities, remote accommodations, and HVAC system pre-heating. The examination incorporates advanced MATLAB simulations to assess energy-exergy performance and cost viability. At lower Re values, both energy ([Formula: see text]) and exergy ([Formula: see text]) efficiencies increase uniformly; however, stabilization and decline occur at higher Re values. The maximum [Formula: see text] for the PRJDPSAC is 4.38% under a temperature rise parameter of 60 × 10-3 Km2/W for obtaining optimum values of Xjp/Dhd = 1.32, Hjp/Dhd = 0.22, and Yjp/Dhd = 1.32, which is 31% higher than that of the smooth double-pass solar air collector (DPSAC). Economic benefits are significant for PRJDPSAC within mair (0.01-0.07 kg/s), but above 0.07 kg/s, the DPSAC becomes more cost-effective. Integrating simulation and experimental data, the study highlights MATLAB's effectiveness for solar energy system analysis and optimization, reinforcing the practicality of the proposed collector design.

Nucleation and Layer Closure Behavior of Iridium Films Grown Using Atomic Layer Deposition.

Understanding the initial growth process during atomic layer deposition (ALD) is essential for various applications employing ultrathin films. This study investigated the initial growth of ALD Ir films using tricarbonyl-(1,2,3-η)-1,2,3-tri(tert-butyl)-cyclopropenyl-iridium and O2. Isolated Ir nanoparticles were formed on the oxide surfaces during the initial growth stage, and their density and size were significantly influenced by the growth temperature and substrate surface, which strongly affected the precursor adsorption and surface diffusion of the adatoms. Higher-density and smaller nanoparticles were formed at high temperatures and on the Al2O3 surface, forming a continuous Ir film with a smaller thickness, resulting in a very smooth surface. These findings suggest that the initial growth behavior of the Ir films affects their surface roughness and continuity and that a comprehensive understanding of this behavior is necessary for the formation of continuous ultrathin metal films.

Enhancing the performance of a solar air heater by employing the broken V-shaped ribs.

This work aims to enhance the performance of a solar air heater (SAH) by introducing broken V-ribs as roughness elements on the absorber plate. The unit with a conventional flat absorber plate is referred to as the "FSAH," while the unit with a broken V-rib-shaped absorber plate is called the "VSAH." The experiment was performed for three air velocities: 25 m/s, 20 m/s, and 15 m/s and the corresponding air flow rates were 0.037 kg/s, 0.031 kg/s, and 0.023 kg/s, respectively. The results showed that the maximum temperature was experienced on the absorber plate, followed by the glass plate for both SAHs. Overall, the average absorber and glass plate temperatures of the VSAH were 0.6-1.4 °C and 0.4-1.9 °C lower than those of the FSAH. Compared to the FSAH, the experimental results showed that the VSAH experienced useful power and thermal efficiency that were 16.6-19.8% and 15.7-20.4% higher, respectively, while the top surface heat losses were found to decrease by 2.1-8.1%. Due to the disrupted air paths in the VSAH, the observed pressure drop was 113.3-133.3% higher than that of the FSAH. More impotently, the thermo-hydraulic performance factor was always higher 1 and the observed values were 1.48, 1.39, and 1.24 at the va (velocity) values of 15, 20, and 25 m/s, respectively. Therefore, the proposed VSAH had an admirable thermal performance as compared to FSAH. Further, optimization through varying the roughness parameters, namely, relative blockage width (W/w), relative pitch ratio (P/e), number of baffles (n), relative blockage height (e/H), and angle of attack (ß) could helped to achieve better performance.

Crystallization-based upcycling of iron oxyhydroxide for efficient arsenic capture in contaminated soils.

Arsenic (As)-contaminated soil inevitably exists in nature and has become a global challenge for a sustainable future. Current processes for As capture using natural and structurally engineered nanomaterials are neither scientifically nor economically viable. Here, we established a feasible strategy to enhance As-capture efficiency and ecosystem health by structurally reorganizing iron oxyhydroxide, a natural As stabilizer. We propose crystallization to reorganize FeOOH-acetate nanoplatelets (r-FAN), which is universal for either scalable chemical synthesis or reproduction from natural iron oxyhydroxide phases. The r-FAN with wide interlayer spacing immobilizes As species through a synergistic mechanism of electrostatic intercalation and surface chemisorption. The r-FAN rehabilitates the ecological fitness of As-contaminated artificial and mine soils, as manifested by the integrated bioassay results of collembolan and plants. Our findings will serve as a cornerstone for crystallization-based material engineering for sustainable environmental applications and for understanding the interactions between soil, nanoparticles, and contaminants.

Recognition of IoT-based fire-detection system fire-signal patterns applying fuzzy logic.

In Korea, the use of fire-detection systems applying IoT technology to existing analog fire-alarm systems has increased owing to the communication technology convergence, the world's best Internet network, and the proliferation of Internet of Things (IoT). Its use can be expected to increase worldwide in the future. For IoT-based fire-detection systems to exhibit the requisite reliability (based on a low false-alarm rate), research related to the analysis of detection signals should be actively promoted and conducted. However, there has been no research activity based on actual operational data, apart from the research that has been conducted in laboratory environments. The primary reason for this state of affairs has been that the installation and use of IoT-based fire-detection systems on a large scale has been rare, worldwide. Consequently, with respect to the fire-signal characteristics of IoT-based fire-detection systems, related data in this study were obtained by investigating actual fire accident cases, using fire alarm data that occurred over a period of 5 years. Based on the signal pattern analysis results using these field data, a fuzzy logic system for recognizing fire signal patterns was developed and verified. As a result, in the actual fire accidents examined, an "alarm" condition-corresponding to the high possibility of fire among the five fire alarms-was determined 30 s before the actual fire alarm. Moreover, it was also found that approximately 80% of non-fire alarms could be reduced in the actual fire alarms that occurred at Institute K during the 5-year period examined.

Experimental investigation and optimization of dimple-roughened impinging jet solar air collector using a novel AHP-MABAC approach.

The effect of the flow and geometric parameters of a dimple-roughened absorber plate on the enactment of solar air collectors (SACs) with air-impinged jets was investigated in this study. The performance-defining criteria (PDCs) of a jet-impinged dimple-roughened SAC (JIDRSAC)-forced convection airflow system are significantly affected by variations in the system's control factors (CFs), such as the arc angle (αaa) ranging from 30° to 75°, dimple pitch ratio (pd/Dh) ranging from 0.269 to 1.08, and dimple height ratio (ed/Dh) ranging from 0.016 to 0.0324. The constant parameters of the jet slot are a stream-wise pitch ratio (Xi/Dhd) is 1.079, a span-wise pitch ratio (Yi/Dhd) is 1.619, and a jet diameter(Di/Dhd) is 0.081. Based on the combined approach of the analytic hierarchy process and multi-attributive border approximation area comparison (AHP-MABAC), the Reynolds number (Re) = 15,000, αaa = 60°, pd/Dh = 0.27, and ed/Dh = 0.027 depicted the best alternative (A-9) set among 16 alternatives to deliver the optimal performance of the JIDRSAC. The jet impingement pass compared to the smooth pass, the Nusselt number increased by 2.16-2.81, and friction factor increased by 3.35-5.95, and JIDRSAC was compared to the jet impingement pass, exhibiting an enhancement in Nusselt number and friction factor in the range of 0.55-0.80 and 0.05-0.15, respectively. In addition, sensitivity analysis is used to examine the ranking's stability and reliability in relation to the PDC weights.

Accumulation of biomedical waste during the COVID-19 pandemic: concerns and strategies for effective treatment.

This study deals with the pollution impact of biomedical waste (BMW) generation due to the COVID-19 pandemic at both the global and national levels. This discussion is important in light of clear scientific evidence that, apart from the airborne transmission of the disease, the virus also survives on different surfaces and poses the risk of infection. Moreover, an investigation is conducted on BMW generation in tons/day in India during the COVID-19 period, with implications for future projection. Additionally, a pioneering study was conducted to estimate the usage of facemasks during the COVID-19 pandemic in India. This paper also provides a feasible solution, by adopting a modern perspective, towards managing BMW generated in the context of SARS-CoV-2 at isolation wards and crematoriums. Strategical approaches have been suggested for segregating and safely disposing BMW. The latest availability of disposal facilities is discussed based on source data provided by the Central Pollution Control Board (CPCB), India. Among the many disposal methods, incineration technologies are examined in depth. The impact of existing incineration technology on the environment and human health has been extensively studied. This study suggests strategies for controlling BMW generation during the COVID-19 pandemic.

Future refrigerants with low global warming potential for residential air conditioning system: a thermodynamic analysis and MCDM tool optimization.

Increasing CO2 emission due to the practicing of high global warming potential (GWP) refrigerant like R22 in split air conditioning (AC) units needs the best substitute to match with environment and safety protocols along with good energy efficiency. In this study, 14 alternative refrigerants have been chosen to replace R22 in a 1.5 TR capacity of split AC from the existing studies. The performance of each refrigerant has been analysed thermodynamically and compared their results with R22 by accounting for discharge temperature, power consumption, coefficient of performance (COP), total equivalent warming impact (TEWI) index, and life-time cost. Overall from this theoretical analysis, it was observed that the best refrigerant for each considered measure is not unique; for example, R290 was best in terms of refrigerant charge and discharge pressure, while R444B was chosen to be superior in terms of COP, TEWI, and life-time cost. Therefore, a multi-criteria decision-making methodology tool-based optimization has been carried out for selecting a single superior refrigerant for the future by considering thermal properties, COP, TEWI, and life-time cost. Results of the evaluation based on the distance from average solution envisage R290 and R1123 as superior and worst choices to replace R22.

Bioaccumulation and Mass Balance Analysis of Veterinary Antibiotics in an Agricultural Environment.

Veterinary antibiotics (VAs) released into the environment are a concern because of the possibility for increasing antibiotic-resistance genes. The concentrations of six VAs, chlortetracycline, oxytetracycline, tetracycline, sulfamethazine, sulfamethoxazole, and sulfathiazole, in manure-based compost, soil, and crops were measured using liquid chromatography-tandem mass spectrometry. Mass balance analysis was conducted based on the measured antibiotic concentration, cultivation area, and amount of manure-based compost applied. The result showed that the detected mean concentration of VAs ranges was 3.52~234.19 µg/kg, 0.52~13.08 µg/kg, and 1.05~39.57 µg/kg in manure-based compost, soil, and crops, respectively, and the substance of VAs detected in different media was also varied. Mass balance analysis showed that the VAs released from the manure-based compost can remain in soil (at rates of 26% to 100%), be taken up by crops (at rates of 0.4% to 3.7%), or dissipated (at rates of 9% to 73%) during the cultivation period. Among the six VAs, chlortetracycline and oxytetracycline mainly remained in the soil, whereas sulfamethoxazole and sulfathiazole were mainly dissipated. Although we did not verify the exact mechanism of the fate and distribution of VAs in this study, our results showed that these can vary depending on the different characteristics of VAs and the soil properties.

Analysis of Major Bacteria and Diversity of Surface Soil to Discover Biomarkers Related to Soil Health.

The discovery of biomarkers for assessing soil health requires the exploration of organisms that can explain the core functions of soil and identification of species with major roles in these functions. However, identifying specific keystone markers within the soil microbiota is challenging. Next-generation sequencing (NGS)-based molecular-biological methods have revealed information on soil biodiversity; however, whether this biodiversity is related to soil health remains unclear. In this study, we performed NGS on grassland surface soil to compare the prokaryotic and eukaryotic genetic diversity to determine the chemical soil quality and examined markers associated with soil health. Microorganisms associated with the nitrogen cycle, bioremediation, plant pathogenicity, antibiotic production, and material degradation showed potential for use as markers. To propose a framework for soil health assessment, we not only used traditional indicators, such as chemical and physical measures, but also assessed metagenomics data of soil by land use to identify the major factors influencing the microbial structure in soil. Moreover, major keystone species were identified. Furthermore, the microbial genetic diversity of generally healthy surface soil, such as forests, farmland, and parks, was determined. These findings provide basic data for exploring soil health-related biomarkers.

Metastable hexagonal close-packed palladium hydride in liquid cell TEM.

Metastable phases-kinetically favoured structures-are ubiquitous in nature1,2. Rather than forming thermodynamically stable ground-state structures, crystals grown from high-energy precursors often initially adopt metastable structures depending on the initial conditions, such as temperature, pressure or crystal size1,3,4. As the crystals grow further, they typically undergo a series of transformations from metastable phases to lower-energy and ultimately energetically stable phases1,3,4. Metastable phases sometimes exhibit superior physicochemical properties and, hence, the discovery and synthesis of new metastable phases are promising avenues for innovations in materials science1,5. However, the search for metastable materials has mainly been heuristic, performed on the basis of experiences, intuition or even speculative predictions, namely 'rules of thumb'. This limitation necessitates the advent of a new paradigm to discover new metastable phases based on rational design. Such a design rule is embodied in the discovery of a metastable hexagonal close-packed (hcp) palladium hydride (PdHx) synthesized in a liquid cell transmission electron microscope. The metastable hcp structure is stabilized through a unique interplay between the precursor concentrations in the solution: a sufficient supply of hydrogen (H) favours the hcp structure on the subnanometre scale, and an insufficient supply of Pd inhibits further growth and subsequent transition towards the thermodynamically stable face-centred cubic structure. These findings provide thermodynamic insights into metastability engineering strategies that can be deployed to discover new metastable phases.

Energy and environmental analysis of a solar evacuated tube heat pipe integrated thermoelectric generator using IoT.

This paper investigates the solar evacuated tube heat pipe system (SETHP) coupled with a thermoelectric generator (TEG) using the internet of things (IoT). The TEGs convert heat energy into electricity through the Seebeck effect that finds application in the waste heat recovery process for the generation of power. The present work deals with the theoretical study on solar evacuated tube heat pipe integrated TEG and it is validated experimentally using with and without parabolic trough concentrating collector. However, it is found that the maximum power output due to the influence of the parabolic trough concentrator results in increased efficiency when compared with the non-concentrating SETHP-TEG system. Thus, the thermoelectric generator's electrical energy efficiency for the concentrating system was 0.151% greater than the latter one. A power electronic boost converter may enhance the acquired TEG output power to a maximum of 5.98 V. This would be directly used for both mobile charging and lighting applications in distant places and military camps where the community lacks sufficient electrical access. And the carbon credit of the TEG system is determined to find its potential in the environmental aspects of carbon emission per watt, carbon mitigation, and carbon credit and its results are 2.34 × 10-3 g/W, 0.027 tonnes, and 0.681 dollars respectively for a TEG module. Besides, the recorded real sensor data with Arduino is implemented in the experimental process for automatic remote monitoring of the temperature.

Effect of Combined Soil Amendment on Immobilization of Bioavailable As and Pb in Paddy Soil.

Heavy metal pollution in soil can have detrimental effects on soil ecosystems and human health. In situ remediation techniques are widely used to reduce the bioavailable fractions of heavy metals in soil. The main objective of this study was to examine the reduction of the bioavailable fractions of As and Pb in paddy soil with artificial lightweight material (ALM) manufactured from recycled materials. A total of four treatments, including a control (no amendment), ALM10 (10% of ALM in soil), ALM10+L (10% ALM combined with 0.5% lime), and ALM10+FeO (10% ALM combined with 0.5% FeO), were applied to paddy fields, and rice (Oryza sativa L.) was cultivated after 32 weeks. The highest reduction efficiencies for the bioavailable fractions of As and Pb in soil were observed in the ALM10+FeO (52.8%) and ALM10+L treatments (65.7%), respectively. The uptake of As decreased by 52.1% when ALM10+FeO was applied to paddy soil, and that of Pb decreased by 79.7% when ALM10+L was applied. Correlation analysis between bioavailable heavy metals in soil and soil chemical properties showed that soil pH, electrical conductivity (EC), P2O5, and soil organic matter (SOM) were the main factors controlling the mobility and bioavailability of As and Pb. Overall, the efficiencies of As and Pb reduction increased synergistically in both soil and plants when FeO and lime were combined with the ALM. In future studies, long-term monitoring is necessary to examine the longevity of soil amendments.

Exploring the photo-thermal conversion behavior and extinction coefficient of activated carbon nanofluids for direct absorption solar collector applications.

This work aims to explore the optical and thermal conversion characteristics of activated carbon-solar glycol nanofluids with various volume fractions namely 0.2, 0.4, and 0.6%, respectively. Kigelia africana leaves were synthesized into porous activated carbon nanomaterials by using the high-temperature sintering process and the pyrolysis process in a muffle furnace. The experimental investigation was carried out with different nanofluid concentrations by using the solar simulator. Nanofluids were heated with the assistance of a solar simulator test system and the convection/conduction heat loss was decreased by using the glass as an insulating material around the test section. Prepared nanofluid with 0.6 vol% activated carbon augmented the thermal conductivity by 14.36% at 60°C. The maximum temperature difference of 10°C was attained at 0.6% volume concentrations of nanofluid as compared with base fluid (solar glycol). In addition, maximum receiver efficiency of 94.51% was attained at 0.6% volume fractions of activated carbon-based nanofluid compared with solar glycol thru a light radiation time of 600 s. Moreover, activated carbon-based nanofluid exhibited significantly higher absorption efficiency as the majority of the radiation was absorbed by the nanofluid. It is concluded that activated carbon-based nanofluids could be a suitable low-cost highly stable material for developing working fluid for direct absorbance solar collector-based applications.

A novel solar-powered milk cooling refrigeration unit with cold thermal energy storage for rural application.

This experimental study analyzed the use of solar photovoltaic energy for operating a novel twin-circuit DC milk chiller without batteries using water-based cold thermal energy storage for different seasons in Chennai, India. HFC-134a and HC-600a were used as refrigerants in the two individual circuits. For each season, the test was conducted continuously for 18 days to analyze the quantity of generated ice that could be utilized to chill 10 L of milk in the morning and in the evening. The average quantity of ice formed per day in the ice bank during monsoon, winter, and summer seasons was found to be 3.61, 19.75, and 27.97 kg, respectively. Thus, it is evident that the use of solar energy with thermal energy storage is effective for operating the milk chilling unit for two seasons, namely winter and summer. However, the system requires an additional power source for continuous operation during the monsoon season. It is noteworthy to mention that the use of a solar milk chiller instead of a conventional milk chiller resulted in 91.15% lesser CO2 emission with 27.6% less LCC. In this study, solar photovoltaic power was observed to be a good choice for chilling milk in the context of global warming and energy consumption. The use of thermal energy storage also allows the initial cost to be reduced.

Experimental investigations of stability, density, thermal conductivity, and electrical conductivity of solar glycol-amine-functionalized graphene and MWCNT-based hybrid nanofluids.

This research article discusses properties such as density, thermal conductivity, and electrical conductivity of solar glycol with amine-functionalized graphene and multi-walled carbon nanotubes (MWCNTs). The hybrid nanofluid is prepared by dispersing the amine-functionalized graphene (AFG) and MWCNTs (50:50 in % by weight ratio) in pure solar glycol. The AFG and MWCNTs are dispersed in different volume concentrations of 0.05%, 0.1%, and 0.15% through the classical two-step homogenizing technique. Good colloidal stability nanofluid are prepared with Gum Arabic (non-covalent) as the surfactant. The stability of nanofluids is ensured through scanning electron microscopy, UV-Vis spectrometer, and zeta potential analyzer. The nanofluid thermal conductivity is measured with varying the nanomaterial loading from 0.05 to 0.15 vol% using a KD2 pro thermal analyzer. The thermal conductivity and electrical conductivity of nanofluid augmentations are considerably with an increasing volume concentration of AFG and MWCNT loading. The thermal conductivity of the AFG-MWCNT-based hybrid nanofluid is augmented by 8.59% for the maximum concentration of 0.15 vol% at 50 °C. The electrical conductivity of the solar glycol-based nanofluids is enhanced linearly with increased operating temperatures. The maximum electrical conductivity enhancement attained is ~28.85% at a nanoparticle loading of 0.15 vol% and 70 °C.